ON DANGEROUS HEAVY METALS / METALLOIDS IN SOILS
https://doi.org/10.19047/0136-1694-2011-68-56-82
Abstract
According to the current ecotoxicological data of Dutch ecologists, hazardous heavy metals/metalloids in the soil form a number of: Se > Tl > Sb > Cd > V > Hg > Ni > Cu > Cr > As > Ba. This series differs greatly from a number of hazards of heavy elements, adopted in Russia in accordance with GOST 17.4.1.02-83, in which the danger of Pb, Zn, Co in soils is exaggerated, and V, Sb, Ba - underestimated. The list of hazardous elements in the soil should also include to be included in Tl, Cr. The content of heavy metals/metalloids in contaminated soils is studied very unevenly: better 11: Cu, Zn, Pb, Ni, Cd, Cr, As, Mn, Co, Hg, Se; the other 46 were studied much worse, although there are dangerous ones among them: Ba, V, Tl.
In Russia, the information on the content of these elements in soils is not enough, and it is on them that the attention of soil scientists and ecologists should be focused.
References
1. Bazdyrev, G.I.; Pronina, N.B.; Rodriguez, D.R. Heavy metals in the soil-plant system on the sloping lands (in Russian) // Izvestia TSKHA. 2001. Issue. 2. С. 81-104.
2. Bashkin, V.N.; Kurbatova, A.S. Biogeochemical and geo-ecological approaches for the assessment of the complex ecological impact (in Russian) // Modern problems of the soil pollution. Interd. conf., M., 2004. С. 174-176
3. Beznosikov, V.A.; Lodygin, E.D. Estimation of the heavy metals content in the soils of the agricultural lands of the Komi Republic (in Russian) // Modern problems of the soil contamination. Interd. conf., M., 2004. С. 176-178.
4. Bolshakov, V.A.; Belobrov, V.P.; Shishov, L.L. Slovnik. Terms, their brief definition, reference materials on soil ecology, geography and soil classification. M.: Soil int-It. V.V., V.V., "THE SOIL ECOLOGY, GEOGRAPHY AND SOIL CLASSIFICATION". Dokuchaeva, 2004. 138 с.
5. Borisochkina, T.I.; Vodyanitskiy, Yu.N. Heavy metal pollution of the agro-landscapes of Russia: sources, scales, forecasts (in Russian) // Bul. Soil int-ta n.a. V.V. Dokuchaeva. 2007. № 60. С. 82-89.
6. Varshal, G.M.; Velukhanova, T.K.; Chetiya, D.N.; Guminovye Acids as a natural complex-forming sorbent concentrating heavy metals in the objects of environment (in Russian) // Geochemical barriers in the zone of hypregenesis. Interd. Symposium. М., 1999. С. 51-53
7. Verikhov, B.V. Hygienic assessment of the chemical impact on the condition of the musculoskeletal system in children in industrial cities of the Perm region. Autoref. ...Diss. candidate of medical sciences. Perm, 2007. 27 с.
8. Vitkovskaya, S.E.; Drichko, V.F. Surma in the environment (in Russian) // Agrochemistry. 1998. № 6. С. 86-90
9. Vodianitskiy Y.N. Heavy and superheavy metals and metalloids in contaminated soils. M.: Soil int-It im. V.V., V.V., V.V., V.V., V.V., V.V., V.V., V.V., V.V., ZH. Dokuchaeva. 2009а. 182 с.
10. Vodianitskiy, Yu.N. Functional differences of the heavy and superheavy metals and metalloids in soils (in Russian) // Bul. Soil int-ta n.a. V.V. Dokuchaeva. 2009б. Issue. 64. С. 50-56.
11. Vodianitskiy, Yu.N. Chromium and arsenic in the polluted soils (in Russian) // Soil science. 2009в. № 5. С. 551-559
12. Vodianitskiy Yu.N. Condition and behavior of the natural and anthropogenic forms As, Sb, Se, Te in ore dumps and polluted soils // Soil science. 2010. № 1. С. 37-46.
13. Vodianitskiy, Yu.N. Chemical aspects of the uranium behavior in soils (literature review) // Soil science. 2011. № 8. С. 940-952
14. Vodianitskiy, Yu.N.; Vasiliev, A.A.; Vlasov, M.N. Hydrogen pollution with heavy metals of alluvial soils in Perm // Soil science. 2008. № 11. С. 1399-1408.
15. Vodianitskiy, Yu.N.; Vasiliev, A.A.; Savichev, A.A.; Chashchin, A.N. Influence of the man-caused and natural factors on the heavy metals content in the soils of the Middle Urals (Chusovoy and vicinities) // Soil science. 2010a. № 5. С. 1089-1099
16. Vodianitskiy Yu.N., Savichev, A.T., Vasiliev, A.A., Lobanova, E.S., Chashchin, A.N., Prokopovich, E.V. Heavy alkaline-earth (Sr, Ba) and rare-earth (Y, La, Ce) metals content in technogenic-contaminated soils // Soil science. 2010б. № 7. С. 879-890.
17. Harmful chemical substances. Inorganic compounds of elements of I-IV groups. L.: Chemistry, 1988. 512 с.
18. Homonova N.F. Ecological and agrochemical functions of fertilizers at their long application (50 years) in agrocenosis on sod-podzolic soil. Autoref. dis. ...Doctor of Biol. М., 2010. 48 с
19. GUEST 17.4.1.02-83. Nature protection. Soils. Classification of chemical substances for pollution control. М., 1983. 12 с.
20. Greenwood N., Ernsho A. Element chemistry. Т. 2. M.: Binom, 2008. 670 с
21. State report on the state and protection of the environment of the Russian Federation in 2007. Moscow: Ministry of Natural Resources of the Russian Federation, 2008. 503 с.
22. Dmitrakov, L.M.; Dmitrakova, L.K.; Abashina, N.A.; Pinskiy, D.L. Lead influence on the oat morphometric indices (in Russian) // Agrochemistry. 2004. № 8. С. 48-53.
23. Dobrovolskiy, V.V. (in Russian) // Agrochemistry. 2004. Geography of microelements. Global dispersion. M.: Thought, 1983. 271 с
24. Dobrovolsky V.V. Hypregenesis of the quaternary period. Moscow: Nedra, 1966.
25. Dobrovolsky V.V. Fundamentals of biogeochemistry. MOSCOW: ACADEMIA, 2003. 396 с.
26. Evreinova, A.V.; Popovich, A.A. Kolesnikov, S.I. Application of the biological activity indicators for monitoring and diagnostics of soil contamination with heavy metals of II class of hazard (in Russian) // Modern problems of soil contamination. Interd. conf. M., 2004. С. 207-208.
27. Elkina, G.Ya. Approaches to the rationing of the heavy metals content in the podzolic soils (in Russian) // Modern problems of soil contamination. II Intermediate conf. M., 2007. Т. 2. С. 55-59
28. Zhornyak L.V. Ecological and geochemical assessment of the territory of Tomsk according to the data of soil studies. Autoref. dis. ...Cand. of Sciences. Tomsk, 2009. 22 с.
29. Ivanov V.V. Ecological geochemistry of elements. Book. 1-6. Moscow: Subsoil-Ecology, 1994-1997.
30. Ilyin, V.B. About the heavy metals pollution of soils and agricultural crops by the nonferrous metallurgy enterprise (in Russian) // Agrochemistry, 1990. № 3. С. 92-98.
31. Ilyin, V.B. Estimation of the existing standards of the heavy metals content in the soil (in Russian) // Agrochemistry. 2000. № 9. С. 74-79.
32. Ilyin, V.B.; Konarbayeva, G.A. Talliy in the soils of the south of Western Siberia (in Russian) // Soil science. 2000. № 6. С. 701-705.
33. Kabata-Pendias A., Pendias H. Microelements in soils and plants. M.: Mir, 1989.
34. Kovalskiy, V.V. Geochemical ecology. Moscow: Science, 1974
35. Kovalskiy V.V. Geochemical ecology. Moscow: Science, 1974
36. Kolesnikov, S.I. Ranking of the chemical elements according to the degree of their ecological danger (in Russian) // Modern problems of the soil pollution. III Intern. conf., M., 2010. С. 362-365.
37. Linnik, P.N.; Nabivanets, B.I. Forms of metal migration in fresh water. L.: Hydrometeoizdat, 1986. 269 с.
38. Matveev, Yu.M.; Avdonkin, A.A. Approaches to the rationing of the arsenic impact (load) on the soil cover of the Russian Federation (in Russian) // Modern problems of soil contamination. II Intern. conf., M., 2007. Т. 2. С. 118-122
39. Methodical guidelines on determination of heavy metals in soils of agricultural lands and crop production. M.: CINAO, 1989. 58 с
40. Motuzova G.V., Bezuglova O.S. Ecological monitoring of soils. M.: Gaudemus, 2007. 237 с.
41. Obukhov, A.I. Ecological consequences of the soil pollution with the heavy metals and measures for their elimination (in Russian) // Polluant behavior in soils and landscapes. Pushchino, 1990. С. 52-59.
42. Okolelova, A.A.; Shishkunov, V.M.; Nadtochiy, I.V. About the assessment of the Volgograd soil pollution with heavy metals (in Russian) // Modern problems of the soil pollution. II Intermediate conf. M.: 2007. Т. 2. С. 137-140
43. Oreshkin, V.N. Direct atomic-absorption method of determination of the heavy metals in the environmental objects for the purposes of geochemistry and pollution control // Pollutant behavior in soils and landscapes. Pushchino, 1990. С. 60-73.
44. Pavlova N.N., Egorova E.I. Some indicators of biological activity of the soil microorganisms as indicators of anthropogenic pollution of soils by heavy metals and radionuclides // Modern problems of soil contamination. II Intermediate conf. M., 2007. Т. 2. С. 146-148
45. Plekhanova I.O. Self-purification of sandy loamy sod-podzolic soils at polyethylene pollution as a result of application of sewage sludge // Modern problems of soil contamination. II Intern. conf., M., 2007. T. I., 2007. С. 198-202.
46. Ponizovskiy, A.A.; Mironenko, E.V. Lead absorption mechanisms (II) by the soils (in Russian) // Soil science. 2001. № 4. С. 418-429
47. Abstract magazine. Soil science and agrochemistry. Moscow: VINITI Publishing House, 2010. №№ 1-12.
48. Savenko, V.S.; Savenko, A.V. Experimental methods for studying the low-temperature geochemical processes. M.: GEOS, 2009. 302 с.
49. State of the environment. United Nations Environment Programme. Moscow: VINITI Publishing House, 1980. 162 с.
50. Sudnitsin, I.I.; Kurenina, I.I.; Frontalsieva, M.V.; Pavlov, S.S. Soil chemistry in Moscow and Dubna (in Russian) // Agrochemistry. 2009. № 7. С. 66-70.
51. Explanatory dictionary on soil science / Editor-in-chief. A.A. Rode. Moscow: Science, 1975. 286. с
52. Khomyakov, D.M. To the question on the estimation of the pollution level and the condition of the urban soils (in Russian) // Modern problems of the soil pollution. III Intern. conf., M., 2010. С. 53-57.
53. Chernikh, N.A.; Ovcharenko, M.M. Heavy metals and radionuclides in biogeocenoses. M.: Agroconsult, 2002. 197 с
54. Anawar H.M., Akai J., Mostofa K.M.G., Safiullah S., Tareq S.M. Arsenic poisoning in groundwater: health risk and geochemical sources in Bangladesh // Environ. Intern. 2002. V. 27. P. 597-604.
55. Bowen H. J. M. Trace elements in biochemistry. London-N.Y.: Acad. Press, 1966. 241 p.
56. Bowen H. J. M. Enwironmental chemistry of elements. N.Y.: Acad. Press, 1979. 333 p.
57. Brown G.E., Foster A.L., Ostergren J.D. Mineral surface and bioavailability of heavy metals: A molecular-scale perspective // Proc. Natl. Acad. Sci. USA. 1999. V. 96. P. 3388-3395.
58. Crommentuijn T., Polder M.D., Van de Plassche E.J. Maximum Permissible Concentrations and Negligible Concentrations for metals, taking background concentrations into account // RIVM Report 601501001. Bilthoven, Netherlands. 1997. 260 p.
59. Eary L.E., Rai D. Chromate reduction by subsurface soils under acidic conditions // Soil Sci. Soc. Am. J. 1991. V. 55. P. 676-683
60. Filliela M., Belzile N., Chen Y.W. Antimony in the environment: a review focused on natural waters. II. Relevant solution chemistry // Earth-Sci. Rev. 2002. V. 59. P. 265-285
61. Fredrickson J.K., Kostandarithes H.M., Li S.W., Plymale A.E., Daly M.J. Reduction of Fe(III), Cr(VI), U(VI) and Tc(VII) by Deinococcus radiodurans R1 // Appl. Environ. Microb. 2000. V. 66. P. 2006-2011
62. James B.R., Bartlett R.J. Behavoir of chromium in soils. 5. Fate of organically complexed Cr(III) added to soil // Environ. Sci. Technol. 1983. V. 12. P. 169-172.
63. Jones K.T., Thallium // Heavy metals in soils / Ed. Alloway J.B. N. Y.: John Wiley & Sons, 1990. P. 304-309.
64. Hooda P.S. A special issue on heavy metals in soils: editorial foreword // Adv. Environ. Res. 2003. V. 8. P. 1-3.
65. LaCoste C., Robinson B., Brooks R., Anderson C., Chiarucci A., Leblanc M. The phytoremediation potential of thalliumcontaminated soils using Iberis and Biscutella species // Int. J. Phytorem. 1999. V. 1. P. 327-338
66. Leuz A.-K., Monch H., Johnson C.A. Sorption of Sb (III) and Sb (V) to goethite: Influence on Sb(III) oxidation and mobilization // Environ. Sci. Technol. 2006. V. 40. P. 7277-7282.
67. Leuz A.-K., Johnson C.A. Oxidation of Sb (III) to Sb (V) by O2 and H2O2 in aqueous solutions // Geochim. Cosmohim. Acta. 2005. V. 69. P. 1165-1172.
68. Lin T.S., Nriagu J. Thallium speciation in the Great Lakes // Envir. Sci. Technol. 1999. V. 33. P. 3394-3397
69. Mаnceau A., Boisset M.C., Sarret G., Hazemann J.L., Mench M., Cambier P., Prost R. Direct determination of lead speciation in contaminated soils by EXAFS spectroscopy // Environ. Sci. Technol. 1996. V. 30. P. 1540-1552.
70. Mаnceau A., Marcus M.A., Tamura N. Quantative speciation of heavy metals in soils and sediments by synchrotron X-ray techniques // Applications of Synchrotron Radiation in Low-Temperature Geochemistry and Enviromental Science. Reviews in Mineralogy and Geochemistry. Washington, DC. 2002. V. 49. P. 341-428
71. Mаnceau A., Marcus M.A., Tamura N., Prous O., Geoffroy N., Lanson B. Natural speciation of Zn at the micrometer scale in a clay soil using X-ray fluorescence, absorption, and diffraction // Geocim. Cosmochim. Acta. 2004. V. 68. P. 2467-2483.
72. Mаndal B.K., Suzuki K.T. Arsenic round the world: A review // Talanta. 2002. V. 58. P. 210-235
73. McArthur J.M., Ravenscroft P., Safiulla S., Thirlwall M.F. Arsenic in groundwater: testing pollution mechanisms for sedimentary aquifer in Bangladesh // Water Resour. 2001. V. 37. P. 109-117
74. Mengel K., Kirkby E.A. Principles of plant nutrition. Bern: Int. Potash Inst., 1987. 687 p.
75. Mitsunobu S., Harada T., Takahashi Y. Comparison of antimony behavior with that of arsenic under various soil redox conditions // Environ. Sci. Technol. 2006. V. 40. P. 7270-7276
76. Morin G., Ostergren J.D., Juillot F., Ildefonse P., Calas G., Brown J.E. XAFS determination of the chemical form of lead in smelter-contaminated soils and mine tailings: Importance of adsorption process // Am. Mineral. 1999. V. 84. P. 420-434
77. Nickson R.T., McArhtur J.M., Ravenscroft P., Burgess W.C., Ahmed K.M. Mechanism of arsenic release to groundwater Bangladesh and West Bengal // Appl. Geochem. 2000. V. 15. P. 403-413
78. Patterson R.R., Fendorf S., Fendorf M. Reduction of hexavalent chromium by amorphous iron sulfide // Environ. Sci. Technol. 1997. V. 31. P. 2039-2044.
79. Park C.H., Keyhan M., Wielinga B.W., Fendorf S., Matin A. Purification to homogeneity and characterization of novel Pseudomonas pytida chromate reductase // Appl. Environ. Microbial. 2000. V. 66. P. 1788-1795
80. Pavlickova J., Zbiral J., Smatanova M., Habarta P., Houserova P., Kuban V. Uptake of thallium from artificially contaminated soils by kale (Brassica oleracea L. var. acephala) // Plant Soil Environ. 2006. V. 52. P. 544-549
81. Pavlickova J., Zbiral J., Smatanova M., Habarta P., Houserova P., Kuban V. Uptake of thallium from artificially and naturally contaminated soils into rape (Brassica napus L.) // J. Agr. Food Chem. 2005. V. 53. P. 2867-2871
82. Pedersen H.D., Postma D., Jakobsen R. Release of arsenic associated with the reduction and transformation of iron oxides // Geochim. Cosmochim. Acta. 2006. V. 70. P. 4116-4129.
83. Ryser A.L., Strawn D.G., Marcus M.A., Fakra S., Johnson-Maynard J.L., Moller G. Microscopically focused synchrotron X-ray investigation of selenium speciation in soils developing on reclaimed mine lands // Environ. Sci. Technol. 2006. V. 40. P. 462-467
84. Sass B.M., Rai D. Solubility of amorphous chromium(III)-iron(III) hydroxide solid solution // Inorg. Chem. 1987. V. 26. P. 2228-2232.
85. Scheinost A.C., Rossberg A., Vantelon D., Xifra I.O., Krerzchmar R., Leuz A.-K., Funke H., Johnson C.A. Quantitative antimony speciation in shooting-range soils by EXAFS spectroscopy // Geochim. Cosmochim. Acta. 2006. V. 70. P. 3299-3312.
86. Smedley P.L., Kinniburgh D.C. A review of the source, behavior and distribution of arsenic in natural waters // Appl. Geochem. 2002. V. 17. P. 517-568.
87. Smedley P.L., Zhang M., Zhang G., Luo Z. Mobilization of review of arsenic and other trace elements in fluviolacustrine aquiefers of the Huhhot Basin, Inner Mongolia // Appl. Geochem. 2003. V. 18. P. 1453-1477
88. Tareq S.M., Safiulla S., Anawar H.M., Rahman M.M., Ishizuka T. Arsenic pollution in groundwater: a self-organizing complex geochemical process in deltaic sedimentary environment, Bangladesh // Sci. Total Environ. 2003. V. 313. P. 213-226.
89. Tighe M., Lockwood P., Wilson S. Adsorption of antimony(V) by floodplain soils, amorphous iron(III) hydroxide and humic acid // J. Environ. Monit. 2005. V. 7. P. 1177-1185.
90. Van de Plassche E.J., De Bruijn J.H.M. Towards integrated environmental quality objectives for surface water, sediments and soil for nine metals. RIVM Report 679101005. Netherlands: Bilthoven, 1992. 130 p
91. Wierzbicka M., Szarek-Lukaszewska G., Grodzinska M. Highly toxic thallium in plant the vicinity of Olkusz (Poland) // Ecotox. Environ. Saf., 2004. V. 59. P. 84-88.
92. Wood J.M. Biological cycles for toxic elements in the environment // Science. 1974. V. 183. P. 1049-1069.
93. Zitco V. Toxicity and pollution potential of thallium // Sci. Total Environ. 1975. V. 4. P. 185-192.
Review
For citations:
Vodianitsky Yu. ON DANGEROUS HEAVY METALS / METALLOIDS IN SOILS. Dokuchaev Soil Bulletin. 2011;(68):56-82. (In Russ.) https://doi.org/10.19047/0136-1694-2011-68-56-82
Views:
1268
Email this article 
