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SOIL CHEMISTRY TRENDS

https://doi.org/10.19047/0136-1694-2010-66-64-82

Abstract

In modern soil chemistry, four main directions are being actively developed: 1) chemistry of organic matter, 2) biochemical processes in soils, 3) chemical basis of soil protection, 4) soil study as
chemical membrane and a pool of chemical elements. Interest to the study of organic matter, soil contamination and the role of soil as a chemical component of the environment reflects pragmatic trends in modern soil chemistry. Many advances in soil chemistry are now associated with the use of new nonspecific methods of analysis, primarily physical ones. The greatest progress has been made in
identification of individual chemical compounds in soil when using synchrotron X-ray technology.

About the Author

Yu. Vodianitsky
V.V. Dokuchaev Soil Science Institute
Russian Federation


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99. Lovley D.R. Organic matter mineralization with the reduction of ferric iron: a review // Geomicrobiology J. 1987. V. 5. № 3/4. P. 375-399.

100. Schulze D.G., Sutton S.R., Bajt S. Determing manganese oxidation state in soils using X-ray absorption near-edge structure (XANES) spectroscopy // Soil Sci. Soc. Am. J. 1995. V. 59. P. 1540-1548.

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102. Sutton S.R., Rivers M.L. Hard X-ray synchrotron microprobe techniques and applications // Synchrotron X-ray methods in clay science / Eds.: D. Schulse, P. Bertsch, J. Stucki. 1999. P. 146-163.

103. Lovley D.R., Phillips E.J.P. Organic matter mineralization with reduction of iron in anaerobic sediments // Appl. Environ. Microbiol. 1986. V. 51. P. 683-689.

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105. Lovley D.R., Phillips E.J.P. Novel mode of microbial energy metabolism: organic carbon oxidation coupled to dissimilatory reduction of iron or manganese // Appl. Environ. Microbiol. 1988. V. 54. P. 1472-1480.

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107. Mаnceau A., Boisset M.C., Sarret G., Hazemann J.L., Mench M., Cambier P., Prost R. Direct determination of lead speciation in contaminated soils by EXAFS spec-troscopy // Environ. Sci. Technol. 1996. V. 30. P. 1540-1552.

108. Waychunas G.A., Rea B.A., Fuller C.C., Davis J.A. Surface chemistry of ferrigydrite: Part 1. EXAFS studies of the geometry of coprecipitated and adsorbed arsenate // Geochim. Cosmochim. Acta. 1993. V. 57. P. 2251-2269.

109. Mаnceau A., Lanson B., Schlegel M.L., Harge J.C., Musso M., Eybert-Berard L., Hazemann J-L., Chateigner D., Lamble G.M. Quantitative Zn speciation in smelter-contaminated soils by EXAFS spectroscopy // American J. Sci. 2000. V. 300, P. 289-343.

110. Xia K., Weesner F., Bleam W.F., Bloom P.R., Skyllberg U.L., Helmke P.A. XANES studies of oxidation states of sulfur in aquatic and soil humic substances // Soil Sci. Soc. Am. J. 1998. V. 62. P. 1240-1246.

111. Mаnceau A., Marcus M.A., Tamura N. Quantative speciation of heavy metals in soils and sediments by synchrotron X-ray techniques // Applications of Synchrotron Radiation in Low-Temperature Geochemistry and Enviromental Science. Reviews in Mineralogy and Geochemistry. Washington, 2002. V. 49. P. 341-428.

112. Mаnceau A., Tamura N., Celestre R.S., Macdowell A.A. Geoffroy N., Sposito G., Padmore H.A. Molecular-scale speciation of Zn and Ni soil ferromanganese nodules from loess soils of the Mississippi Basin // Environ. Sci. Technol. 2003. V. 37. P. 75-80.

113. Morin G., Juillot F., Casiot C., Bruneel O., Persone J.-C., Elbaz-Poulichet F., Leblanc M., Ildefonse P., Calas G. Bacterial formation of tooeleite and mixed arsenic (III) or arsenic (V) - iron (III) gels in the Carnoules acid mine drainage, France. A XANES, XRD, and SEM study // Environ. Sci. Technol. 2003. V. 37. P. 1705-1712.

114. Morin G., Ostergren J.D., Juillot F., Ildefonse P., Calas G., Brown J.E. XAFS determination of the chemical form of lead in smelter-contaminated soils and mine tailings: Importance of adsorption process // Am. Mineral. 1999. V. 84. P. 420-434.

115. Morra M.G., Fendorf S.E., Brown P.D. Speciation of sulfur in humic and fulvic acids using X-ray absorption near-edge structure (XANES) spectroscopy // Geochim. Cosmohim. Acta. 1997. V. 61. P. 683-688.

116. Nowack B., Obrecht J.-M. Schluep M., Schulin R., Hansmann W., Koppel V. Elevated lead and zinc contents in remote alpine soils of the Swiss National Park // J. Environ. Qual. 2001. V. 30. P. 919-926.

117. Olmez I., Sholkovitz E.R., Hermann D., Eganhouse R.P. Rare earth elements in sediments off Southern California: A new Anthropogenic indicator // Environ. Sci. Technol. 1991. V. 25. P. 310-331.

118. Paktung D., FosterА., Laflamme G. Speciation and characterization of arsenic in Ketza River mine tailings using X-ray adsorptoin spectroscopy // Environ. Sci. Technol. 2003. V. 37. P. 2067-2074.

119. Roden E.E. Fe(III) oxide reactivity toward biological versus chemical reduction. Environ. Science Technol. 2003. V. 37. P. 1319-1324.

120. Savichev A.T., Vodyanitskii Yu.N. Determination of barium, lanthanum and cerium contents in soil by X-ray radiometric method // Eurasian Soil Sci. 2009. № 13. Р. 1461-1469.

121. Scheinost A.C., Krerzchmar R.S., Prister S., Roberts D.R. Combining selective sequential extractions, X-ray absorptoin spectroscopy, and principal component analysis for quantitative zinc speciation in soil // Environ. Sci. Technol. 2002. V. 36. P. 5021-5028.

122. Shelobolina E.S., Anderson R.T., Vodyanitskii Y.N., Sivtsov A.V., Vuretich R., Lovley D.R. Importance of clay size minerals for Fe(III) respiration in a petrolium-contaminated aquifer // Geobiology. 2004. V. 2. Р. 67-76.

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Vodianitsky Yu. SOIL CHEMISTRY TRENDS. Dokuchaev Soil Bulletin. 2010;(66):64-82. (In Russ.) https://doi.org/10.19047/0136-1694-2010-66-64-82

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