The sessile drop method was used to measure the contact angle of wetting (CA) of ordinary Chernozem from the fields of the Kamennaya Steppe agrolandscape used in various ways. The treatments differ in the intensity of tillage operations (protected mowed steppe, arable land after moldboard plowing), the use of mineral fertilizers and their aftereffect, as well as changes in soil properties under the influence of irrigation. At the same time, the total organic carbon content, C/N ratio, specific surface area, and rheological parameters were determined for the physical and chemical characteristics of soils. The results of the study showed that the hydrophilic-hydrophobic properties of the surface of the solid phase of soils, which largely determine the main structure-forming properties of soils, can be characterized by the value of the wetting edge angle. The CA of the studied soil samples varies from 32 degrees (highest wettability) to 45 degrees (lowest wettability). The lowest wettability is due to the increased content of hydrophobic compounds in the organic matter of soils and is characterized by the highest CA and is typical for native, untreated soil of the mowed steppe, which differs from other studied variants of the experiment in all explored physical and chemical parameters. Moldboard plowing as well as fallowing lead to changes in the physical and chemical properties of the soil and the qualitative composition of organic matter in the direction of their deterioration and a decrease in the CA. The use of mineral fertilizers contributes to the increase in the studied indicator mainly due to changes in plant productivity, in particular, the differences in CA are due to the impact of root secretions and plant residues on the soil properties. For the studied soils, the CA changes in the following series: mowed steppe > arable land with the mineral fertilizers application > arable land undergone the aftereffect of fertilizers. Correlation analysis revealed the relationship of CA with organic carbon content, specific surface area, and rheological characteristics of Chernozems. Thus, CA can serve as an integral indicator of changes in the physical and chemical properties of soils, their degradation changes under the conditions of different agricultural load. The method used in this research for determining CA requires a smaller amount of sample compared to rheological methods and is generally more informative than determining the content of organic matter.
In soils of Ili Alatau (dark kastanozems, light kastanozems, mountain chernozems) both in continuous cropping system of sugar beet and in crop rotation with prolonged use of fertilizers the soil agrochemical indices, phosphorus reserves and group composition (total, organic and mineral) vary significantly. The total phosphorus content in the soils was 1720–2330 mg/kg and decreased in the series: virgin mountain chernozems > arable dark kastanozems > arable mountain chernozems > light kashtanozems > virgin dark kastanozems. It was observed, that in arable dark kastanozems, as compared to virgin soils, the content of available forms of phosphorus (loose-bound phosphates Ca-PI and miscellaneous calcium phosphates Ca-PII) increased, and the content of plant unavailable forms of phosphorus (poorly soluble Ca phosphates Ca-PIII, phosphates of aluminum Al-P and iron Fe-P) decreased. In arable mountain chernozems, in comparison with virgin mountain chernozems, the content of all fractions of phosphorus decreased. Arable light kastanozems contain the least amount of available phosphates and the highest of phosphates of aluminum and iron. When cultivating beets on light kastanozems, the content of all fractions of phosphorus, except iron phosphates, increased with increasing dose of fertilizers. The effectiveness of the application of the organic-mineral fertilizers was comparable to the introduction of NK + P1.5 and NK + P2, the yield of sugar beet in the crop rotation in these variants is the highest and amounts to 614 and 577 centner/ha; in the control value (obtained without fertilizers) – 197 centner/ha, and in the variant with application of only NK fertilizers – 277 centner/ha. In continuous cropping system these values were 576 and 561 centner/ha; 311 and 327 centner/ha respectively. Close values of crop yield were obtained in two variants: with the organo-mineral system and NK + P1.5, due to the additional use by the plants of sugar beet phosphorus of newly formed organic compounds.
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